{"id":7128,"date":"2024-07-16T14:35:17","date_gmt":"2024-07-16T06:35:17","guid":{"rendered":"\/\/www.shigann.com\/?p=7128"},"modified":"2024-07-16T14:35:17","modified_gmt":"2024-07-16T06:35:17","slug":"%e4%b8%81%e5%9f%ba%e7%a1%ab%e9%86%87%e9%94%a1%e5%90%88%e6%88%90%e6%96%b9%e6%b3%95%e4%b8%8e%e5%b7%a5%e8%89%ba","status":"publish","type":"post","link":"\/\/www.shigann.com\/7128.html","title":{"rendered":"\u4e01\u57fa\u786b\u9187\u9521\u5408\u6210\u65b9\u6cd5\u4e0e\u5de5\u827a"},"content":{"rendered":"<h3 data-spm-anchor-id=\"5176.28103460.0.i43.1e5b3da2xzb0IO\">\u4e01\u57fa\u786b\u9187\u9521\u7684\u5408\u6210\u65b9\u6cd5\u4e0e\u5de5\u827a<\/h3>\n<p>\u4e01\u57fa\u786b\u9187\u9521\uff08Butylmercaptostannane\uff09\uff0c\u5316\u5b66\u5f0fC4H10OSSn\uff0c\u662f\u4e00\u79cd\u5e38\u7528\u7684\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u4e3b\u8981\u7528\u4e8e\u805a\u6c2f\u4e59\u70ef\uff08PVC\uff09\u7684\u7a33\u5b9a\u5242\uff0c\u56e0\u5176\u4f18\u79c0\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u900f\u660e\u6027\u800c\u53d7\u5230\u9752\u7750\u3002\u4e0b\u9762\u5c06\u63a2\u8ba8\u51e0\u79cd\u4e01\u57fa\u786b\u9187\u9521\u7684\u5178\u578b\u5408\u6210\u65b9\u6cd5\u53ca\u5176\u5de5\u827a\u6d41\u7a0b\u3002<\/p>\n<h4>\u5408\u6210\u8def\u7ebf\u4e4b\u4e00\uff1a\u4e01\u57fa\u6c2f\u5316\u9521\u4e0e\u786b\u9187\u7684\u53cd\u5e94<\/h4>\n<p>\u8fd9\u662f\u5408\u6210\u4e01\u57fa\u786b\u9187\u9521\u5e38\u89c1\u7684\u65b9\u6cd5\u4e4b\u4e00\u3002\u4e01\u57fa\u6c2f\u5316\u9521\uff08BuSnCl3\uff09\u4f5c\u4e3a\u8d77\u59cb\u539f\u6599\uff0c\u4e0e\u4e01\u57fa\u786b\u9187\uff08BuSH\uff09\u5728\u9002\u5f53\u7684\u6eb6\u5242\u548c\u6e29\u5ea6\u4e0b\u8fdb\u884c\u53cd\u5e94\uff0c\u751f\u6210\u4e01\u57fa\u786b\u9187\u9521\u3002\u8be5\u53cd\u5e94\u53ef\u4ee5\u8868\u793a\u4e3a\uff1a<\/p>\n<p><span class=\"math math-inline\"><span class=\"katex\"><span class=\"katex-mathml\">BuSnCl3+BuSH\u2192Bu2SnS+3HCl<\/span><span class=\"katex-html\" aria-hidden=\"true\"><span class=\"base\"><span class=\"mord\"><span class=\"mord text\">BuSnCl<\/span><span class=\"msupsub\"><span class=\"vlist-t vlist-t2\"><span class=\"vlist-r\"><span class=\"vlist\"><span class=\"sizing reset-size6 size3 mtight\"><span class=\"mord mtight\">3<\/span><\/span><\/span><span class=\"vlist-s\">\u200b<\/span><\/span><\/span><\/span><\/span><span class=\"mbin\">+<\/span><\/span><span class=\"base\"><span class=\"mord text\"><span class=\"mord\">BuSH<\/span><\/span><span class=\"mrel\">\u2192<\/span><\/span><span class=\"base\"><span class=\"mord\"><span class=\"mord text\">Bu<\/span><span class=\"msupsub\"><span class=\"vlist-t vlist-t2\"><span class=\"vlist-r\"><span class=\"vlist\"><span class=\"sizing reset-size6 size3 mtight\"><span class=\"mord mtight\">2<\/span><\/span><\/span><span class=\"vlist-s\">\u200b<\/span><\/span><\/span><\/span><\/span><span class=\"mord text\"><span class=\"mord\">SnS<\/span><\/span><span class=\"mbin\">+<\/span><\/span><span class=\"base\"><span class=\"mord\">3<\/span><span class=\"mord text\"><span class=\"mord\">HCl<\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n<h5>\u5de5\u827a\u6b65\u9aa4\uff1a<\/h5>\n<ol>\n<li><strong>\u539f\u6599\u51c6\u5907<\/strong>\uff1a\u5c06\u4e01\u57fa\u6c2f\u5316\u9521\u548c\u4e01\u57fa\u786b\u9187\u6309\u4e00\u5b9a\u6bd4\u4f8b\u79f0\u91cf\uff0c\u540c\u65f6\u51c6\u5907\u597d\u5e72\u71e5\u7684\u53cd\u5e94\u5bb9\u5668\u548c\u6eb6\u5242\u3002<\/li>\n<li><strong>\u53cd\u5e94\u6761\u4ef6\u63a7\u5236<\/strong>\uff1a\u5728\u6c2e\u6c14\u4fdd\u62a4\u4e0b\uff0c\u5c06\u539f\u6599\u6eb6\u89e3\u4e8e\u6eb6\u5242\u4e2d\uff0c\u5982\u4e8c\u6c2f\u7532\u70f7\u6216\u56db\u6c22\u544b\u5583\uff0c\u7136\u540e\u5728\u6e29\u548c\u7684\u52a0\u70ed\u6761\u4ef6\u4e0b\u6405\u62cc\u6df7\u5408\u7269\u3002<\/li>\n<li><strong>\u526f\u4ea7\u7269\u53bb\u9664<\/strong>\uff1a\u53cd\u5e94\u5b8c\u6210\u540e\uff0c\u901a\u8fc7\u8fc7\u6ee4\u6216\u84b8\u998f\u7684\u65b9\u5f0f\u9664\u53bb\u672a\u53cd\u5e94\u7684\u539f\u6599\u548c\u526f\u4ea7\u7269\uff0c\u5982\u76d0\u9178\u53ef\u4ee5\u901a\u8fc7\u6c34\u6d17\u7b49\u65b9\u5f0f\u9664\u53bb\u3002<\/li>\n<li><strong>\u4ea7\u54c1\u7eaf\u5316<\/strong>\uff1a\u901a\u8fc7\u67f1\u5c42\u6790\u3001\u7ed3\u6676\u6216\u84b8\u998f\u7b49\u624b\u6bb5\u8fdb\u4e00\u6b65\u63d0\u7eaf\u4ea7\u54c1\u3002<\/li>\n<li><strong>\u6210\u54c1\u68c0\u9a8c<\/strong>\uff1a\u4ea7\u54c1\u9700\u8fdb\u884c\u8d28\u91cf\u68c0\u6d4b\uff0c\u5305\u62ec\u7eaf\u5ea6\u3001\u989c\u8272\u3001\u6bd4\u91cd\u548c\u6298\u5149\u7387\u7b49\u6307\u6807\u7684\u6d4b\u5b9a\uff0c\u4ee5\u786e\u4fdd\u7b26\u5408\u6807\u51c6\u3002<\/li>\n<\/ol>\n<h4>\u5408\u6210\u8def\u7ebf\u4e4b\u4e8c\uff1a\u4e01\u57fa\u9521\u9187\u4e0e\u786b\u5316\u6c22\u7684\u53cd\u5e94<\/h4>\n<p>\u53e6\u4e00\u79cd\u5408\u6210\u9014\u5f84\u662f\u5229\u7528\u4e01\u57fa\u9521\u9187\uff08Bu2SnOH\uff09\u4e0e\u786b\u5316\u6c22\uff08H2S\uff09\u53cd\u5e94\uff0c\u751f\u6210\u4e01\u57fa\u786b\u9187\u9521\u3002\u53cd\u5e94\u65b9\u7a0b\u5f0f\u5982\u4e0b\uff1a<\/p>\n<p><span class=\"math math-inline\"><span class=\"katex\"><span class=\"katex-mathml\">Bu2SnOH+H2S\u2192Bu2SnS+H2O<\/span><span class=\"katex-html\" aria-hidden=\"true\"><span class=\"base\"><span class=\"mord\"><span class=\"mord text\">Bu<\/span><span class=\"msupsub\"><span class=\"vlist-t vlist-t2\"><span class=\"vlist-r\"><span class=\"vlist\"><span class=\"sizing reset-size6 size3 mtight\"><span class=\"mord mtight\">2<\/span><\/span><\/span><span class=\"vlist-s\">\u200b<\/span><\/span><\/span><\/span><\/span><span class=\"mord text\"><span class=\"mord\">SnOH<\/span><\/span><span class=\"mbin\">+<\/span><\/span><span class=\"base\"><span class=\"mord\"><span class=\"mord text\">H<\/span><span class=\"msupsub\"><span class=\"vlist-t vlist-t2\"><span class=\"vlist-r\"><span class=\"vlist\"><span class=\"sizing reset-size6 size3 mtight\"><span class=\"mord mtight\">2<\/span><\/span><\/span><span class=\"vlist-s\">\u200b<\/span><\/span><\/span><\/span><\/span><span class=\"mord text\"><span class=\"mord\">S<\/span><\/span><span class=\"mrel\">\u2192<\/span><\/span><span class=\"base\"><span class=\"mord\"><span class=\"mord text\">Bu<\/span><span class=\"msupsub\"><span class=\"vlist-t vlist-t2\"><span class=\"vlist-r\"><span class=\"vlist\"><span class=\"sizing reset-size6 size3 mtight\"><span class=\"mord mtight\">2<\/span><\/span><\/span><span class=\"vlist-s\">\u200b<\/span><\/span><\/span><\/span><\/span><span class=\"mord text\"><span class=\"mord\">SnS<\/span><\/span><span class=\"mbin\">+<\/span><\/span><span class=\"base\"><span class=\"mord\"><span class=\"mord text\">H<\/span><span class=\"msupsub\"><span class=\"vlist-t vlist-t2\"><span class=\"vlist-r\"><span class=\"vlist\"><span class=\"sizing reset-size6 size3 mtight\"><span class=\"mord mtight\">2<\/span><\/span><\/span><span class=\"vlist-s\">\u200b<\/span><\/span><\/span><\/span><\/span><span class=\"mord text\"><span class=\"mord\">O<\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n<h5>\u5de5\u827a\u6b65\u9aa4\uff1a<\/h5>\n<ol>\n<li><strong>\u539f\u6599\u6df7\u5408<\/strong>\uff1a\u5728\u60f0\u6027\u6c14\u4f53\u73af\u5883\u4e0b\uff0c\u5c06\u4e01\u57fa\u9521\u9187\u4e0e\u786b\u5316\u6c22\u6c14\u4f53\u6df7\u5408\u3002<\/li>\n<li><strong>\u53cd\u5e94\u50ac\u5316<\/strong>\uff1a\u53ef\u80fd\u9700\u8981\u50ac\u5316\u5242\uff08\u5982\u9178\u6216\u78b1\uff09\u4fc3\u8fdb\u53cd\u5e94\u8fdb\u884c\u3002<\/li>\n<li><strong>\u4ea7\u7269\u5206\u79bb<\/strong>\uff1a\u901a\u8fc7\u84b8\u998f\u6216\u5176\u4ed6\u7269\u7406\u65b9\u6cd5\u5206\u79bb\u51fa\u4ea7\u7269\u548c\u672a\u53cd\u5e94\u7684\u539f\u6599\u3002<\/li>\n<li><strong>\u7cbe\u5236<\/strong>\uff1a\u91c7\u7528\u9002\u5f53\u7684\u65b9\u6cd5\u53bb\u9664\u6742\u8d28\uff0c\u63d0\u9ad8\u4ea7\u7269\u7eaf\u5ea6\u3002<\/li>\n<\/ol>\n<h4>\u5de5\u827a\u6ce8\u610f\u4e8b\u9879\uff1a<\/h4>\n<ul>\n<li><strong>\u5b89\u5168\u8003\u91cf<\/strong>\uff1a\u4e01\u57fa\u786b\u9187\u9521\u7684\u5408\u6210\u8fc7\u7a0b\u4e2d\u6d89\u53ca\u5230\u7684\u539f\u6599\u548c\u526f\u4ea7\u7269\u53ef\u80fd\u5177\u6709\u8150\u8680\u6027\u6216\u6bd2\u6027\uff0c\u64cd\u4f5c\u65f6\u5fc5\u987b\u7a7f\u6234\u9002\u5f53\u7684\u4e2a\u4eba\u9632\u62a4\u88c5\u5907\uff0c\u5e76\u5728\u901a\u98ce\u826f\u597d\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c\u3002<\/li>\n<li><strong>\u53cd\u5e94\u6761\u4ef6<\/strong>\uff1a\u63a7\u5236\u53cd\u5e94\u6e29\u5ea6\u3001\u538b\u529b\u548c\u6eb6\u5242\u7684\u9009\u62e9\u5bf9\u53cd\u5e94\u7684\u6548\u7387\u548c\u4ea7\u54c1\u7684\u7eaf\u5ea6\u81f3\u5173\u91cd\u8981\u3002<\/li>\n<li><strong>\u73af\u4fdd\u63aa\u65bd<\/strong>\uff1a\u53cd\u5e94\u4ea7\u751f\u7684\u526f\u4ea7\u7269\u5982\u76d0\u9178\u6216\u6c34\u9700\u8981\u7ecf\u8fc7\u9002\u5f53\u7684\u5904\u7406\uff0c\u907f\u514d\u5bf9\u73af\u5883\u9020\u6210\u6c61\u67d3\u3002<\/li>\n<\/ul>\n<h4>\u7ed3\u8bed<\/h4>\n<p data-spm-anchor-id=\"5176.28103460.0.i45.1e5b3da2xzb0IO\">\u4e01\u57fa\u786b\u9187\u9521\u7684\u5408\u6210\u662f\u4e00\u4e2a\u6d89\u53ca\u591a\u6b65\u5316\u5b66\u53cd\u5e94\u7684\u8fc7\u7a0b\uff0c\u9700\u8981\u7cbe\u786e\u63a7\u5236\u53cd\u5e94\u6761\u4ef6\u548c\u5de5\u827a\u53c2\u6570\u3002\u5728\u5de5\u4e1a\u751f\u4ea7\u4e2d\uff0c\u8fd8\u9700\u8981\u8003\u8651\u6210\u672c\u6548\u76ca\u3001\u73af\u5883\u4fdd\u62a4\u548c\u5b89\u5168\u89c4\u8303\u7b49\u56e0\u7d20\uff0c\u4ee5\u5b9e\u73b0\u9ad8\u6548\u3001\u7eff\u8272\u548c\u53ef\u6301\u7eed\u7684\u751f\u4ea7\u76ee\u6807\u3002\u4e0d\u540c\u7684\u5408\u6210\u8def\u7ebf\u9002\u7528\u4e8e\u4e0d\u540c\u7684\u751f\u4ea7\u89c4\u6a21\u548c\u9700\u6c42\uff0c\u9009\u62e9\u9002\u5b9c\u7684\u5de5\u827a\u6d41\u7a0b\u662f\u6210\u529f\u7684\u5173\u952e\u3002<\/p>\n<p data-spm-anchor-id=\"5176.28103460.0.i45.1e5b3da2xzb0IO\">\n<p>\u6269\u5c55\u9605\u8bfb\uff1a<\/p>\n<p><a href=\"https:\/\/www.cyclohexylamine.net\/cas2212-32-0\/\"><u>CAS:2212-32-0 \u2013 Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine \u2013 Shanghai Ohans Co., LTD<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.cyclohexylamine.net\/nn-dicyclohexylmethylamine\/\"><u>N,N-Dicyclohexylmethylamine \u2013 Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine \u2013 Shanghai Ohans Co., LTD<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/44326\"><u>bismuth neodecanoate\/CAS 251-964-6 \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/814\"><u>stannous neodecanoate catalysts \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/44772\"><u>polyurethane tertiary amine catalyst\/Dabco 2039 catalyst \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.morpholine.org\/dmcha\/\"><u>DMCHA &#8211; morpholine<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.morpholine.org\/n-methylmorpholine\/\"><u>N-Methylmorpholine &#8211; morpholine<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.bdmaee.net\/polycat-41-catalyst-cas10294-43-5-evonik-germany\/\"><u>Polycat 41 catalyst CAS10294-43-5 Evonik Germany \u2013 BDMAEE<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.bdmaee.net\/polycat-dbu-catalyst-cas6674-22-2-evonik-germany\/\"><u>Polycat DBU catalyst CAS6674-22-2 Evonik Germany \u2013 BDMAEE<\/u><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e01\u57fa\u786b\u9187\u9521\u7684\u5408\u6210\u65b9\u6cd5\u4e0e\u5de5\u827a \u4e01\u57fa\u786b\u9187\u9521\uff08Butylmercaptostannane\uff09\uff0c\u5316\u5b66\u5f0fC4H10OSSn\uff0c\u662f\u4e00\u79cd\u5e38\u7528\u7684\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u4e3b\u8981\u7528\u4e8e\u805a\u6c2f\u4e59\u70ef\uff08PVC\uff09\u7684\u7a33\u5b9a\u5242\uff0c\u56e0\u5176\u4f18\u79c0\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u900f\u660e\u6027\u800c\u53d7\u5230\u9752\u7750\u3002\u4e0b\u9762\u5c06\u63a2\u8ba8\u51e0\u79cd\u4e01\u57fa\u786b\u9187\u9521\u7684\u5178\u578b\u5408\u6210\u65b9\u6cd5\u53ca\u5176\u5de5\u827a\u6d41\u7a0b\u3002 \u5408\u6210\u8def\u7ebf\u4e4b\u4e00\uff1a\u4e01\u57fa\u6c2f\u5316\u9521\u4e0e\u786b\u9187\u7684\u53cd\u5e94 \u8fd9\u662f\u5408\u6210\u4e01\u57fa\u786b\u9187 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/posts\/7128"}],"collection":[{"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/comments?post=7128"}],"version-history":[{"count":1,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/posts\/7128\/revisions"}],"predecessor-version":[{"id":7129,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/posts\/7128\/revisions\/7129"}],"wp:attachment":[{"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/media?parent=7128"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/categories?post=7128"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/tags?post=7128"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}