{"id":7155,"date":"2024-07-18T15:54:30","date_gmt":"2024-07-18T07:54:30","guid":{"rendered":"\/\/www.shigann.com\/?p=7155"},"modified":"2024-07-18T15:54:30","modified_gmt":"2024-07-18T07:54:30","slug":"%e6%97%a0%e6%b0%b4%e5%9b%9b%e6%b0%af%e5%8c%96%e9%94%a1%e5%8c%96%e5%ad%a6%e5%8f%8d%e5%ba%94%e6%9c%ba%e7%90%86","status":"publish","type":"post","link":"\/\/www.shigann.com\/7155.html","title":{"rendered":"\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u5316\u5b66\u53cd\u5e94\u673a\u7406"},"content":{"rendered":"<p data-spm-anchor-id=\"5176.28103460.0.i122.1e5b3da2xzb0IO\">\u65e0\u6c34\u56db\u6c2f\u5316\u9521\uff08SnCl4\uff09\uff0c\u4f5c\u4e3a\u4e00\u79cd\u591a\u529f\u80fd\u7684\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\uff0c\u53c2\u4e0e\u4e86\u591a\u79cd\u5316\u5b66\u53cd\u5e94\uff0c\u5176\u50ac\u5316\u673a\u7406\u590d\u6742\u4e14\u591a\u6837\uff0c\u53d6\u51b3\u4e8e\u5177\u4f53\u7684\u53cd\u5e94\u7c7b\u578b\u548c\u6761\u4ef6\u3002\u4ee5\u4e0b\u5c06\u6df1\u5165\u63a2\u8ba8\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u5728\u51e0\u79cd\u5e38\u89c1\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u4f5c\u7528\u53ca\u5176\u53ef\u80fd\u7684\u673a\u7406\u3002<\/p>\n<h3>1. \u6c2f\u5316\u53cd\u5e94\u673a\u7406<\/h3>\n<p>\u5728\u6709\u673a\u5408\u6210\u4e2d\uff0c\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u5e38\u7528\u4e8e\u4fc3\u8fdb\u6709\u673a\u5e95\u7269\u7684\u6c2f\u5316\u53cd\u5e94\u3002\u4f8b\u5982\uff0c\u5f53\u5b83\u4f5c\u4e3a\u6c2f\u5316\u5242\u65f6\uff0c\u5176\u673a\u7406\u53ef\u80fd\u6d89\u53ca\u4ee5\u4e0b\u6b65\u9aa4\uff1a<\/p>\n<ul>\n<li><strong>\u751f\u6210\u6d3b\u6027\u6c2f\u5316\u5242<\/strong>\uff1a\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u4e0e\u6c2f\u6c14\u53cd\u5e94\u751f\u6210\u66f4\u6d3b\u6cfc\u7684\u6c2f\u5316\u5242\uff0c\u5982SnCl5\u2212\u6216SnCl62\u2212\u7b49\u591a\u6c2f\u5408\u7269\uff0c\u8fd9\u4e9b\u591a\u6c2f\u5408\u7269\u80fd\u591f\u66f4\u5bb9\u6613\u5730\u5c06\u6c2f\u539f\u5b50\u8f6c\u79fb\u5230\u6709\u673a\u5e95\u7269\u4e0a\u3002<\/li>\n<li><strong>\u5e95\u7269\u7684\u4eb2\u6838\u53d6\u4ee3<\/strong>\uff1a\u751f\u6210\u7684\u6d3b\u6027\u6c2f\u5316\u5242\u4e0e\u5e95\u7269\u53d1\u751f\u4eb2\u6838\u53d6\u4ee3\u53cd\u5e94\uff0c\u4ece\u5e95\u7269\u4e2d\u53d6\u4ee3\u4e00\u4e2a\u6c22\u539f\u5b50\u6216\u5176\u5b83\u57fa\u56e2\uff0c\u4ece\u800c\u5f15\u5165\u6c2f\u539f\u5b50\u3002<\/li>\n<li><strong>\u518d\u751f\u50ac\u5316\u5242<\/strong>\uff1a\u53cd\u5e94\u5b8c\u6210\u540e\uff0c\u91ca\u653e\u51fa\u7684SnCl4\u53ef\u4ee5\u518d\u6b21\u53c2\u4e0e\u65b0\u7684\u53cd\u5e94\u5faa\u73af\uff0c\u4fdd\u6301\u50ac\u5316\u5242\u7684\u6d3b\u6027\u3002<\/li>\n<\/ul>\n<h3>2. \u8131\u6c34\u53cd\u5e94\u673a\u7406<\/h3>\n<p>\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u5728\u8131\u6c34\u53cd\u5e94\u4e2d\u7684\u4f5c\u7528\u4e3b\u8981\u4f53\u73b0\u5728\u4fc3\u8fdb\u5206\u5b50\u95f4\u6216\u5206\u5b50\u5185\u7684\u8131\u6c34\u8fc7\u7a0b\uff0c\u5f62\u6210\u916f\u3001\u916e\u3001\u5185\u916f\u7b49\u3002\u5176\u673a\u7406\u53ef\u80fd\u5305\u62ec\uff1a<\/p>\n<ul>\n<li><strong>\u5f62\u6210\u4e2d\u95f4\u4f53<\/strong>\uff1a\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u4e0e\u5e95\u7269\u4e2d\u7684\u7f9f\u57fa\u6216\u7fa7\u57fa\u5f62\u6210\u7a33\u5b9a\u7684\u914d\u5408\u7269\uff0c\u964d\u4f4e\u8131\u6c34\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\u3002<\/li>\n<li><strong>\u4fc3\u8fdb\u8131\u6c34<\/strong>\uff1a\u5728\u914d\u5408\u7269\u5f62\u6210\u540e\uff0c\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u901a\u8fc7\u5176Lewis\u9178\u6027\u4fc3\u4f7f\u6c34\u5206\u5b50\u7684\u79bb\u53bb\uff0c\u4ece\u800c\u5b9e\u73b0\u8131\u6c34\u3002<\/li>\n<li><strong>\u4ea7\u7269\u91ca\u653e\u4e0e\u50ac\u5316\u5242\u518d\u751f<\/strong>\uff1a\u4e00\u65e6\u8131\u6c34\u5b8c\u6210\uff0c\u4ea7\u7269\u5f62\u6210\uff0c\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u4ece\u914d\u5408\u7269\u4e2d\u91ca\u653e\uff0c\u91cd\u65b0\u8fdb\u5165\u50ac\u5316\u5faa\u73af\u3002<\/li>\n<\/ul>\n<h3>3. \u5f02\u6784\u5316\u53cd\u5e94\u673a\u7406<\/h3>\n<p>\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u5728\u5f02\u6784\u5316\u53cd\u5e94\u4e2d\u7684\u4f5c\u7528\u673a\u5236\u53ef\u80fd\u6d89\u53ca\u5230\uff1a<\/p>\n<ul>\n<li><strong>\u7a33\u5b9a\u8fc7\u6e21\u6001<\/strong>\uff1a\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u4e0e\u5e95\u7269\u5f62\u6210\u8fc7\u6e21\u6001\u590d\u5408\u7269\uff0c\u901a\u8fc7\u5176Lewis\u9178\u6027\u7a33\u5b9a\u8be5\u72b6\u6001\uff0c\u4f7f\u5f02\u6784\u5316\u8fc7\u7a0b\u66f4\u5bb9\u6613\u8fdb\u884c\u3002<\/li>\n<li><strong>\u63a7\u5236\u53cd\u5e94\u8def\u5f84<\/strong>\uff1a\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u80fd\u591f\u9009\u62e9\u6027\u5730\u4e0e\u5e95\u7269\u7684\u7279\u5b9a\u90e8\u5206\u7ed3\u5408\uff0c\u5f15\u5bfc\u53cd\u5e94\u6cbf\u7740\u6240\u9700\u7684\u8def\u5f84\u8fdb\u884c\uff0c\u4ece\u800c\u63a7\u5236\u4ea7\u7269\u7684\u7acb\u4f53\u5316\u5b66\u3002<\/li>\n<\/ul>\n<h3>4. \u52a0\u6210\u53cd\u5e94\u673a\u7406<\/h3>\n<p>\u5728\u52a0\u6210\u53cd\u5e94\u4e2d\uff0c\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u7684\u4f5c\u7528\u53ef\u80fd\u6d89\u53ca\uff1a<\/p>\n<ul>\n<li><strong>\u6d3b\u5316\u5e95\u7269<\/strong>\uff1a\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u901a\u8fc7\u914d\u4f4d\u4f5c\u7528\u6d3b\u5316\u70ef\u70c3\u6216\u7fb0\u57fa\u5316\u5408\u7269\uff0c\u964d\u4f4e\u5176\u53cd\u5e94\u6d3b\u5316\u80fd\u3002<\/li>\n<li><strong>\u4fc3\u8fdb\u52a0\u6210<\/strong>\uff1a\u4e00\u65e6\u5e95\u7269\u88ab\u6d3b\u5316\uff0c\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u534f\u52a9\u5916\u6765\u8bd5\u5242\uff08\u5982\u6c22\u6c14\u3001\u5364\u7d20\u3001\u6c34\u7b49\uff09\u4e0e\u5e95\u7269\u53d1\u751f\u52a0\u6210\u53cd\u5e94\u3002<\/li>\n<li><strong>\u4ea7\u7269\u5f62\u6210\u4e0e\u50ac\u5316\u5242\u91ca\u653e<\/strong>\uff1a\u52a0\u6210\u4ea7\u7269\u5f62\u6210\u540e\uff0c\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u4ece\u590d\u5408\u7269\u4e2d\u8131\u79bb\uff0c\u6062\u590d\u5176\u50ac\u5316\u6d3b\u6027\u3002<\/li>\n<\/ul>\n<h3>5. \u9178\u50ac\u5316\u53cd\u5e94\u673a\u7406<\/h3>\n<p>\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u7684Lewis\u9178\u6027\u4f7f\u5176\u80fd\u591f\u50ac\u5316\u8bb8\u591a\u9178\u50ac\u5316\u7684\u53cd\u5e94\uff0c\u5982\u916f\u5316\u3001\u7f29\u5408\u3001\u5f00\u73af\u7b49\u3002\u5176\u4f5c\u7528\u673a\u5236\u53ef\u80fd\u5305\u62ec\uff1a<\/p>\n<ul>\n<li><strong>\u8d28\u5b50\u8f6c\u79fb<\/strong>\uff1a\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u901a\u8fc7\u63a5\u53d7\u5e95\u7269\u4e2d\u7684\u5b64\u5bf9\u7535\u5b50\uff0c\u4fc3\u8fdb\u8d28\u5b50\u7684\u8f6c\u79fb\uff0c\u52a0\u901f\u9178\u50ac\u5316\u7684\u53cd\u5e94\u3002<\/li>\n<li><strong>\u5e95\u7269\u6d3b\u5316<\/strong>\uff1a\u901a\u8fc7\u4e0e\u5e95\u7269\u5f62\u6210\u914d\u5408\u7269\uff0c\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u589e\u5f3a\u5e95\u7269\u7684\u53cd\u5e94\u6d3b\u6027\uff0c\u964d\u4f4e\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\u3002<\/li>\n<\/ul>\n<h3>\u7efc\u5408\u673a\u7406<\/h3>\n<p>\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u5728\u4e0d\u540c\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u673a\u7406\u5e76\u975e\u5b64\u7acb\u5b58\u5728\uff0c\u800c\u662f\u76f8\u4e92\u5173\u8054\u7684\u3002\u5728\u5f88\u591a\u60c5\u51b5\u4e0b\uff0c\u4e0a\u8ff0\u673a\u7406\u4e2d\u7684\u591a\u4e2a\u6b65\u9aa4\u53ef\u80fd\u540c\u65f6\u53d1\u751f\uff0c\u5171\u540c\u4fc3\u8fdb\u53cd\u5e94\u7684\u8fdb\u884c\u3002\u4f8b\u5982\uff0c\u5728\u67d0\u4e9b\u590d\u6742\u7684\u6709\u673a\u5408\u6210\u4e2d\uff0c\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u53ef\u80fd\u65e2\u4f5c\u4e3a\u6c2f\u5316\u5242\uff0c\u53c8\u4f5c\u4e3a\u8131\u6c34\u5242\u6216\u9178\u50ac\u5316\u5242\uff0c\u901a\u8fc7\u4e00\u7cfb\u5217\u534f\u540c\u4f5c\u7528\u5b9e\u73b0\u76ee\u6807\u4ea7\u7269\u7684\u9ad8\u6548\u5408\u6210\u3002<\/p>\n<h3>\u7ed3\u8bba<\/h3>\n<p>\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u50ac\u5316\u4f5c\u7528\u6d89\u53ca\u591a\u79cd\u673a\u7406\uff0c\u5305\u62ec\u4f46\u4e0d\u9650\u4e8e\u6c2f\u5316\u3001\u8131\u6c34\u3001\u5f02\u6784\u5316\u548c\u52a0\u6210\u7b49\u3002\u901a\u8fc7\u6df1\u5165\u7406\u89e3\u8fd9\u4e9b\u673a\u7406\uff0c\u5316\u5b66\u5bb6\u80fd\u591f\u66f4\u597d\u5730\u8bbe\u8ba1\u548c\u4f18\u5316\u5408\u6210\u8def\u7ebf\uff0c\u63d0\u9ad8\u4ea7\u7269\u7684\u9009\u62e9\u6027\u548c\u6536\u7387\u3002\u7136\u800c\uff0c\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u7684\u5177\u4f53\u4f5c\u7528\u65b9\u5f0f\u53ef\u80fd\u56e0\u53cd\u5e94\u6761\u4ef6\u3001\u5e95\u7269\u6027\u8d28\u548c\u8f85\u52a9\u8bd5\u5242\u7684\u5b58\u5728\u800c\u6709\u6240\u53d8\u5316\uff0c\u56e0\u6b64\u5728\u5e94\u7528\u4e2d\u9700\u7ec6\u81f4\u8003\u8651\u6bcf\u4e2a\u56e0\u7d20\u7684\u5f71\u54cd\uff0c\u4ee5\u786e\u4fdd\u4f73\u7684\u50ac\u5316\u6548\u679c\u3002<\/p>\n<hr \/>\n<p data-spm-anchor-id=\"5176.28103460.0.i123.1e5b3da2xzb0IO\">\u9700\u8981\u6ce8\u610f\u7684\u662f\uff0c\u4e0a\u8ff0\u673a\u7406\u63cf\u8ff0\u662f\u5bf9\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u5728\u6709\u673a\u5408\u6210\u4e2d\u53ef\u80fd\u4f5c\u7528\u65b9\u5f0f\u7684\u6982\u62ec\u603b\u7ed3\uff0c\u5177\u4f53\u53cd\u5e94\u7684\u673a\u7406\u7ec6\u8282\u53ef\u80fd\u4f1a\u6839\u636e\u65b0\u7684\u79d1\u5b66\u7814\u7a76\u6210\u679c\u800c\u6709\u6240\u66f4\u65b0\u6216\u4fee\u6b63\u3002\u56e0\u6b64\uff0c\u5bf9\u4e8e\u7279\u5b9a\u7684\u50ac\u5316\u53cd\u5e94\uff0c\u5efa\u8bae\u67e5\u9605\u65b0\u7684\u79d1\u5b66\u6587\u732e\u4ee5\u83b7\u53d6\u51c6\u786e\u7684\u4fe1\u606f\u3002<\/p>\n<p data-spm-anchor-id=\"5176.28103460.0.i123.1e5b3da2xzb0IO\">\n<p>\u6269\u5c55\u9605\u8bfb\uff1a<\/p>\n<p><a href=\"https:\/\/www.cyclohexylamine.net\/cas2212-32-0\/\"><u>CAS:2212-32-0 \u2013 Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine \u2013 Shanghai Ohans Co., LTD<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.cyclohexylamine.net\/nn-dicyclohexylmethylamine\/\"><u>N,N-Dicyclohexylmethylamine \u2013 Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine \u2013 Shanghai Ohans Co., LTD<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/44326\"><u>bismuth neodecanoate\/CAS 251-964-6 \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/814\"><u>stannous neodecanoate catalysts \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/44772\"><u>polyurethane tertiary amine catalyst\/Dabco 2039 catalyst \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.morpholine.org\/dmcha\/\"><u>DMCHA &#8211; morpholine<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.morpholine.org\/n-methylmorpholine\/\"><u>N-Methylmorpholine &#8211; morpholine<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.bdmaee.net\/polycat-41-catalyst-cas10294-43-5-evonik-germany\/\"><u>Polycat 41 catalyst CAS10294-43-5 Evonik Germany \u2013 BDMAEE<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.bdmaee.net\/polycat-dbu-catalyst-cas6674-22-2-evonik-germany\/\"><u>Polycat DBU catalyst CAS6674-22-2 Evonik Germany \u2013 BDMAEE<\/u><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u65e0\u6c34\u56db\u6c2f\u5316\u9521\uff08SnCl4\uff09\uff0c\u4f5c\u4e3a\u4e00\u79cd\u591a\u529f\u80fd\u7684\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\uff0c\u53c2\u4e0e\u4e86\u591a\u79cd\u5316\u5b66\u53cd\u5e94\uff0c\u5176\u50ac\u5316\u673a\u7406\u590d\u6742\u4e14\u591a\u6837\uff0c\u53d6\u51b3\u4e8e\u5177\u4f53\u7684\u53cd\u5e94\u7c7b\u578b\u548c\u6761\u4ef6\u3002\u4ee5\u4e0b\u5c06\u6df1\u5165\u63a2\u8ba8\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u5728\u51e0\u79cd\u5e38\u89c1\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u4f5c\u7528\u53ca\u5176\u53ef\u80fd\u7684\u673a\u7406\u3002 1. \u6c2f\u5316\u53cd\u5e94\u673a\u7406 \u5728\u6709\u673a\u5408\u6210\u4e2d\uff0c\u65e0\u6c34\u56db\u6c2f\u5316\u9521\u5e38\u7528\u4e8e\u4fc3\u8fdb\u6709\u673a\u5e95\u7269\u7684\u6c2f\u5316\u53cd\u5e94\u3002\u4f8b\u5982\uff0c\u5f53\u5b83\u4f5c\u4e3a\u6c2f\u5316\u5242\u65f6\uff0c\u5176\u673a\u7406\u53ef\u80fd\u6d89 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/posts\/7155"}],"collection":[{"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/comments?post=7155"}],"version-history":[{"count":1,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/posts\/7155\/revisions"}],"predecessor-version":[{"id":7158,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/posts\/7155\/revisions\/7158"}],"wp:attachment":[{"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/media?parent=7155"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/categories?post=7155"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/tags?post=7155"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}