{"id":7237,"date":"2024-09-10T14:14:21","date_gmt":"2024-09-10T06:14:21","guid":{"rendered":"\/\/www.shigann.com\/?p=7237"},"modified":"2024-09-10T14:14:21","modified_gmt":"2024-09-10T06:14:21","slug":"%e4%b8%89%e4%b8%81%e5%9f%ba%e6%b0%a7%e5%8c%96%e9%94%a1%e7%9a%84%e7%94%9f%e7%89%a9%e7%b4%af%e7%a7%af%e6%80%a7%e4%b8%8e%e7%94%9f%e6%80%81%e9%a3%8e%e9%99%a9%e8%af%84%e4%bc%b0%e7%a0%94%e7%a9%b6","status":"publish","type":"post","link":"\/\/www.shigann.com\/7237.html","title":{"rendered":"\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u7684\u751f\u7269\u7d2f\u79ef\u6027\u4e0e\u751f\u6001\u98ce\u9669\u8bc4\u4f30\u7814\u7a76"},"content":{"rendered":"

\u5f15\u8a00
\n\u4e09\u4e01\u57fa\u6c27\u5316\u9521\uff08tributyltin oxide, TBT\uff09\u662f\u4e00\u79cd\u5e38\u7528\u7684\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\uff0c\u56e0\u5176\u5728\u5de5\u4e1a\u4e0a\u7684\u5e7f\u6cdb\u5e94\u7528\u800c\u5907\u53d7\u5173\u6ce8\u3002\u7136\u800c\uff0c\u8fd1\u5e74\u6765\u7814\u7a76\u53d1\u73b0TBT\u5bf9\u73af\u5883\u7279\u522b\u662f\u6c34\u751f\u751f\u6001\u7cfb\u7edf\u5177\u6709\u663e\u8457\u7684\u751f\u7269\u7d2f\u79ef\u6027\u548c\u6bd2\u6027\u6548\u5e94\uff0c\u5f15\u53d1\u4e86\u5bf9\u5176\u751f\u6001\u98ce\u9669\u7684\u62c5\u5fe7\u3002\u672c\u6587\u5c06\u63a2\u8ba8TBT\u7684\u751f\u7269\u7d2f\u79ef\u6027\u53ca\u5176\u5bf9\u751f\u6001\u7cfb\u7edf\u7684\u6f5c\u5728\u98ce\u9669\uff0c\u5e76\u7b80\u8981\u8ba8\u8bba\u76f8\u5173\u7684\u98ce\u9669\u8bc4\u4f30\u65b9\u6cd5\u3002<\/p>\n

\u4e00\u3001\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u7684\u57fa\u672c\u7279\u6027
\n\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u662f\u4e00\u79cd\u65e0\u8272\u6216\u6de1\u9ec4\u8272\u7684\u6db2\u4f53\uff0c\u5316\u5b66\u5f0f\u4e3aC12H27SnO\uff0c\u5206\u5b50\u91cf\u7ea6\u4e3a289.67 g\/mol\u3002TBT\u56e0\u5176\u826f\u597d\u7684\u6eb6\u89e3\u6027\u548c\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u5728\u591a\u4e2a\u9886\u57df\u5f97\u5230\u4e86\u5e7f\u6cdb\u5e94\u7528\uff0c\u5982\u6d82\u6599\u3001\u5851\u6599\u7a33\u5b9a\u5242\u3001\u519c\u836f\u548c\u6297\u83cc\u5242\u7b49\u3002<\/p>\n

\u4e8c\u3001\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u7684\u751f\u7269\u7d2f\u79ef\u6027
\n\u751f\u7269\u7d2f\u79ef\u6027\u662f\u6307\u5316\u5408\u7269\u5728\u751f\u7269\u4f53\u5185\u79ef\u7d2f\u7684\u7a0b\u5ea6\uff0c\u8fd9\u662f\u8bc4\u4ef7\u5316\u5b66\u7269\u8d28\u73af\u5883\u884c\u4e3a\u7684\u91cd\u8981\u6307\u6807\u4e4b\u4e00\u3002TBT\u56e0\u5176\u8102\u6eb6\u6027\u5f3a\uff0c\u6613\u4e8e\u901a\u8fc7\u98df\u7269\u94fe\u4f20\u9012\uff0c\u8868\u73b0\u51fa\u660e\u663e\u7684\u751f\u7269\u7d2f\u79ef\u6027\u7279\u5f81\u3002<\/p>\n

\u8102\u6eb6\u6027\uff1aTBT\u5177\u6709\u8f83\u5f3a\u7684\u8102\u6eb6\u6027\uff0c\u5bb9\u6613\u88ab\u751f\u7269\u4f53\u5438\u6536\u5e76\u901a\u8fc7\u8102\u80aa\u7ec4\u7ec7\u84c4\u79ef\u3002
\n\u751f\u7269\u5bcc\u96c6\u56e0\u5b50\uff08BAF\uff09\uff1a\u7814\u7a76\u8868\u660e\uff0cTBT\u5728\u67d0\u4e9b\u7269\u79cd\u4e2d\u7684\u751f\u7269\u5bcc\u96c6\u56e0\u5b50\u8f83\u9ad8\uff0c\u8fd9\u610f\u5473\u7740\u5b83\u53ef\u4ee5\u6cbf\u7740\u98df\u7269\u94fe\u9010\u7ea7\u7d2f\u79ef\u3002
\n\u751f\u7269\u653e\u5927\u6548\u5e94\uff1a\u7531\u4e8eTBT\u7684\u751f\u7269\u7d2f\u79ef\u6027\uff0c\u5176\u6d53\u5ea6\u5728\u98df\u7269\u94fe\u4e2d\u9010\u7ea7\u653e\u5927\uff0c\u5bf9\u9876\u7ea7\u6355\u98df\u8005\u9020\u6210\u66f4\u5927\u7684\u5a01\u80c1\u3002
\n\u4e09\u3001\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u7684\u751f\u6001\u6bd2\u6027
\nTBT\u5bf9\u6c34\u751f\u751f\u7269\u5177\u6709\u5f3a\u70c8\u7684\u6bd2\u6027\u4f5c\u7528\uff0c\u5c24\u5176\u662f\u5728\u4f4e\u6d53\u5ea6\u4e0b\u5373\u53ef\u4ea7\u751f\u663e\u8457\u7684\u751f\u6001\u6548\u5e94\u3002<\/p>\n

\u751f\u6b96\u7cfb\u7edf\u5f71\u54cd\uff1aTBT\u5bf9\u8d1d\u7c7b\u7b49\u6d77\u6d0b\u751f\u7269\u5177\u6709\u4e25\u91cd\u7684\u751f\u6b96\u6bd2\u6027\uff0c\u53ef\u5bfc\u81f4\u96c4\u6027\u8d1d\u7c7b\u96cc\u6027\u5316\uff0c\u5f71\u54cd\u79cd\u7fa4\u7684\u7e41\u6b96\u80fd\u529b\u3002
\n\u514d\u75ab\u7cfb\u7edf\u6291\u5236\uff1aTBT\u80fd\u591f\u6291\u5236\u6c34\u751f\u751f\u7269\u7684\u514d\u75ab\u7cfb\u7edf\uff0c\u4f7f\u5b83\u4eec\u66f4\u5bb9\u6613\u53d7\u5230\u75be\u75c5\u4fb5\u88ad\u3002
\n\u795e\u7ecf\u7cfb\u7edf\u635f\u4f24\uff1a\u9ad8\u6d53\u5ea6\u7684TBT\u66b4\u9732\u8fd8\u53ef\u80fd\u5bfc\u81f4\u6c34\u751f\u751f\u7269\u795e\u7ecf\u7cfb\u7edf\u7684\u635f\u4f24\uff0c\u5f71\u54cd\u5176\u884c\u4e3a\u548c\u751f\u5b58\u80fd\u529b\u3002
\n\u56db\u3001\u751f\u6001\u98ce\u9669\u8bc4\u4f30\u65b9\u6cd5
\n\u4e3a\u4e86\u8bc4\u4f30TBT\u5bf9\u751f\u6001\u7cfb\u7edf\u7684\u5f71\u54cd\uff0c\u79d1\u5b66\u5bb6\u4eec\u91c7\u7528\u4e86\u4e00\u7cfb\u5217\u7684\u8bc4\u4f30\u65b9\u6cd5\u3002<\/p>\n

\u73af\u5883\u76d1\u6d4b\uff1a\u5b9a\u671f\u5bf9\u6c34\u4f53\u3001\u5e95\u6ce5\u548c\u751f\u7269\u6837\u672c\u8fdb\u884c\u76d1\u6d4b\uff0c\u4ee5\u786e\u5b9aTBT\u7684\u5b58\u5728\u6c34\u5e73\u548c\u5206\u5e03\u60c5\u51b5\u3002
\n\u5b9e\u9a8c\u5ba4\u6d4b\u8bd5\uff1a\u901a\u8fc7\u5b9e\u9a8c\u5ba4\u57f9\u517b\u8bd5\u9a8c\uff0c\u8bc4\u4f30\u4e0d\u540c\u6d53\u5ea6TBT\u5bf9\u6c34\u751f\u751f\u7269\u7684\u6025\u6027\u6bd2\u6027\u6216\u6162\u6027\u6bd2\u6027\u3002
\n\u6a21\u578b\u9884\u6d4b\uff1a\u5229\u7528\u6570\u5b66\u6a21\u578b\u6a21\u62dfTBT\u5728\u73af\u5883\u4e2d\u7684\u8fc1\u79fb\u3001\u8f6c\u5316\u548c\u7d2f\u79ef\u8fc7\u7a0b\uff0c\u9884\u6d4b\u5176\u5bf9\u751f\u6001\u7cfb\u7edf\u7684\u5f71\u54cd\u8303\u56f4\u3002
\n\u98ce\u9669\u8bc4\u4f30\u6846\u67b6\uff1a\u7efc\u5408\u8003\u8651TBT\u7684\u66b4\u9732\u9014\u5f84\u3001\u6bd2\u6027\u6548\u5e94\u548c\u751f\u6001\u7cfb\u7edf\u654f\u611f\u6027\u7b49\u56e0\u7d20\uff0c\u5efa\u7acb\u5168\u9762\u7684\u98ce\u9669\u8bc4\u4f30\u6846\u67b6\u3002
\n\u4e94\u3001\u7ba1\u7406\u4e0e\u5bf9\u7b56
\n\u9274\u4e8eTBT\u7684\u751f\u6001\u98ce\u9669\uff0c\u56fd\u9645\u4e0a\u5df2\u91c7\u53d6\u591a\u9879\u63aa\u65bd\u9650\u5236\u5176\u4f7f\u7528\u548c\u6392\u653e\u3002<\/p>\n

\u7acb\u6cd5\u9650\u5236\uff1a\u591a\u4e2a\u56fd\u5bb6\u548c\u5730\u533a\u5df2\u7ecf\u7acb\u6cd5\u9650\u5236\u6216\u7981\u6b62TBT\u5728\u9632\u6c61\u6f06\u548c\u5176\u4ed6\u4ea7\u54c1\u4e2d\u7684\u4f7f\u7528\u3002
\n\u66ff\u4ee3\u54c1\u5f00\u53d1\uff1a\u7814\u7a76\u5f00\u53d1\u66f4\u5b89\u5168\u7684\u66ff\u4ee3\u54c1\uff0c\u51cf\u5c11\u5bf9\u73af\u5883\u6709\u5bb3\u7269\u8d28\u7684\u9700\u6c42\u3002
\n\u73af\u5883\u4fee\u590d\uff1a\u5bf9\u4e8e\u5df2\u7ecf\u53d7\u6c61\u67d3\u7684\u533a\u57df\uff0c\u91c7\u53d6\u7269\u7406\u3001\u5316\u5b66\u6216\u751f\u7269\u65b9\u6cd5\u8fdb\u884c\u73af\u5883\u4fee\u590d\u3002
\n\u516c\u4f17\u6559\u80b2\uff1a\u52a0\u5f3a\u516c\u4f17\u5bf9TBT\u7b49\u6709\u5bb3\u7269\u8d28\u7684\u8ba4\u8bc6\uff0c\u63d0\u9ad8\u73af\u5883\u4fdd\u62a4\u610f\u8bc6\u3002
\n\u516d\u3001\u7ed3\u8bba
\n\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u4f5c\u4e3a\u4e00\u79cd\u91cd\u8981\u7684\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\uff0c\u5728\u5de5\u4e1a\u751f\u4ea7\u4e2d\u53d1\u6325\u4e86\u91cd\u8981\u4f5c\u7528\uff0c\u4f46\u5176\u751f\u7269\u7d2f\u79ef\u6027\u548c\u751f\u6001\u6bd2\u6027\u4e5f\u5e26\u6765\u4e86\u663e\u8457\u7684\u73af\u5883\u95ee\u9898\u3002\u901a\u8fc7\u5f00\u5c55\u6df1\u5165\u7684\u751f\u6001\u98ce\u9669\u8bc4\u4f30\u7814\u7a76\uff0c\u5236\u5b9a\u5408\u7406\u7684\u7ba1\u7406\u548c\u4fdd\u62a4\u63aa\u65bd\uff0c\u53ef\u4ee5\u5728\u4fdd\u8bc1\u7ecf\u6d4e\u53d1\u5c55\u7684\u540c\u65f6\u4fdd\u62a4\u751f\u6001\u73af\u5883\uff0c\u5b9e\u73b0\u53ef\u6301\u7eed\u53d1\u5c55\u3002
\n\u6269\u5c55\u9605\u8bfb\uff1a<\/p>\n

cyclohexylamine<\/u><\/a><\/p>\n

Tetrachloroethylene Perchloroethylene CAS:127-18-4<\/u><\/a><\/p>\n

NT CAT DMDEE<\/u><\/a><\/p>\n

NT CAT PC-5<\/u><\/a><\/p>\n

N-Methylmorpholine<\/u><\/a><\/p>\n

4-Formylmorpholine<\/u><\/a><\/p>\n

Toyocat TE tertiary amine catalyst Tosoh<\/u><\/a><\/p>\n

Toyocat RX5 catalyst trimethylhydroxyethyl ethylenediamine Tosoh<\/u><\/a><\/p>\n

NT CAT DMP-30<\/u><\/a><\/p>\n

NT CAT DMEA<\/u><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

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