{"id":7246,"date":"2024-09-11T14:22:08","date_gmt":"2024-09-11T06:22:08","guid":{"rendered":"\/\/www.shigann.com\/?p=7246"},"modified":"2024-09-11T14:22:46","modified_gmt":"2024-09-11T06:22:46","slug":"%e4%b8%89%e4%b8%81%e5%9f%ba%e6%b0%a7%e5%8c%96%e9%94%a1%e5%a4%84%e7%90%86%e6%96%b9%e6%b3%95%e5%8f%8a%e5%85%b6%e5%af%b9%e7%8e%af%e5%a2%83%e7%9a%84%e5%bd%b1%e5%93%8d%e5%88%86%e6%9e%90","status":"publish","type":"post","link":"\/\/www.shigann.com\/7246.html","title":{"rendered":"\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u5904\u7406\u65b9\u6cd5\u53ca\u5176\u5bf9\u73af\u5883\u7684\u5f71\u54cd\u5206\u6790"},"content":{"rendered":"

### \u4e09\u4e01\u57fa\u6c27\u5316\u9521\u5904\u7406\u65b9\u6cd5\u53ca\u5176\u5bf9\u73af\u5883\u7684\u5f71\u54cd\u5206\u6790<\/p>\n

#### \u5f15\u8a00<\/p>\n

\u4e09\u4e01\u57fa\u6c27\u5316\u9521\uff08tributyltin oxide, TBT\uff09\u4f5c\u4e3a\u4e00\u79cd\u5e38\u89c1\u7684\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\uff0c\u5728\u5de5\u4e1a\u3001\u519c\u4e1a\u548c\u65e5\u5e38\u751f\u6d3b\u4e2d\u90fd\u6709\u5e7f\u6cdb\u5e94\u7528\u3002\u7136\u800c\uff0c\u5176\u5bf9\u73af\u5883\u5c24\u5176\u662f\u6c34\u751f\u751f\u6001\u7cfb\u7edf\u7684\u8d1f\u9762\u5f71\u54cd\u5f15\u8d77\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u672c\u6587\u65e8\u5728\u63a2\u8ba8TBT\u7684\u5904\u7406\u65b9\u6cd5\u53ca\u5176\u5bf9\u73af\u5883\u7684\u5f71\u54cd\u3002<\/p>\n

#### \u4e00\u3001\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u7684\u57fa\u672c\u4fe1\u606f<\/p>\n

\u4e09\u4e01\u57fa\u6c27\u5316\u9521\uff08\u5316\u5b66\u5f0f\uff1aC12H27SnO\uff09\uff0c\u662f\u4e00\u79cd\u65e0\u8272\u6216\u6de1\u9ec4\u8272\u7684\u6db2\u4f53\uff0c\u56e0\u5176\u826f\u597d\u7684\u6eb6\u89e3\u6027\u548c\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u5728\u6d82\u6599\u3001\u5851\u6599\u7a33\u5b9a\u5242\u3001\u519c\u836f\u548c\u6297\u83cc\u5242\u7b49\u591a\u4e2a\u9886\u57df\u5f97\u5230\u5e94\u7528\u3002\u4e86\u89e3\u5176\u57fa\u672c\u5c5e\u6027\u5bf9\u4e8e\u540e\u7eed\u7684\u5904\u7406\u548c\u73af\u5883\u8bc4\u4f30\u81f3\u5173\u91cd\u8981\u3002<\/p>\n

#### \u4e8c\u3001\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u7684\u5904\u7406\u65b9\u6cd5<\/p>\n

\u9488\u5bf9TBT\u7684\u5904\u7406\u65b9\u6cd5\uff0c\u4e3b\u8981\u76ee\u7684\u662f\u51cf\u5c11\u5176\u5bf9\u73af\u5883\u7684\u6c61\u67d3\uff0c\u5177\u4f53\u5305\u62ec\u4f46\u4e0d\u9650\u4e8e\u4ee5\u4e0b\u51e0\u79cd\uff1a<\/p>\n

1. **\u7269\u7406\u5904\u7406**\uff1a
\n– **\u5438\u9644\u6cd5**\uff1a\u5229\u7528\u6d3b\u6027\u70ad\u6216\u5176\u4ed6\u591a\u5b54\u6750\u6599\u5438\u9644\u6c34\u4f53\u4e2d\u7684TBT\uff0c\u968f\u540e\u901a\u8fc7\u7269\u7406\u5206\u79bb\u53bb\u9664\u3002
\n– **\u6c89\u6dc0\u6cd5**\uff1a\u52a0\u5165\u5408\u9002\u7684\u6c89\u6dc0\u5242\uff0c\u4f7fTBT\u5f62\u6210\u4e0d\u6eb6\u4e8e\u6c34\u7684\u6c89\u6dc0\u7269\uff0c\u7136\u540e\u901a\u8fc7\u8fc7\u6ee4\u7b49\u65b9\u6cd5\u5206\u79bb\u3002<\/p>\n

2. **\u5316\u5b66\u5904\u7406**\uff1a
\n– **\u6c27\u5316\u8fd8\u539f\u6cd5**\uff1a\u901a\u8fc7\u6dfb\u52a0\u6c27\u5316\u5242\u6216\u8fd8\u539f\u5242\u6539\u53d8TBT\u7684\u5316\u5b66\u5f62\u6001\uff0c\u4f7f\u5176\u8f6c\u5316\u4e3a\u6bd2\u6027\u8f83\u4f4e\u7684\u5316\u5408\u7269\u3002
\n– **\u4e2d\u548c\u6cd5**\uff1a\u5bf9\u4e8e\u9178\u6027\u6216\u78b1\u6027\u73af\u5883\u4e2d\u91ca\u653e\u7684TBT\uff0c\u53ef\u901a\u8fc7\u52a0\u5165\u9002\u5f53\u7684\u78b1\u6216\u9178\u4e2d\u548c\u5904\u7406\uff0c\u964d\u4f4e\u5176\u6bd2\u5bb3\u4f5c\u7528\u3002<\/p>\n

3. **\u751f\u7269\u5904\u7406**\uff1a
\n– **\u5fae\u751f\u7269\u964d\u89e3**\uff1a\u5229\u7528\u67d0\u4e9b\u5fae\u751f\u7269\uff08\u5982\u7ec6\u83cc\u3001\u771f\u83cc\u7b49\uff09\u4ee3\u8c22TBT\u7684\u80fd\u529b\uff0c\u5c06\u5176\u5206\u89e3\u4e3a\u65e0\u5bb3\u6216\u4f4e\u5bb3\u7684\u7269\u8d28\u3002
\n– **\u690d\u7269\u4fee\u590d**\uff1a\u901a\u8fc7\u79cd\u690d\u8010\u53d7\u6027\u8f83\u5f3a\u7684\u690d\u7269\u5438\u6536\u571f\u58e4\u6216\u6c34\u4f53\u4e2d\u7684TBT\uff0c\u5e76\u901a\u8fc7\u690d\u7269\u7684\u4ee3\u8c22\u4f5c\u7528\u8fdb\u884c\u964d\u89e3\u6216\u56fa\u5b9a\u3002<\/p>\n

4. **\u5de5\u7a0b\u5904\u7406**\uff1a
\n– **\u5c01\u95ed\u5faa\u73af\u7cfb\u7edf**\uff1a\u5728\u751f\u4ea7\u548c\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u5efa\u7acb\u5c01\u95ed\u5faa\u73af\u4f53\u7cfb\uff0c\u51cf\u5c11TBT\u7684\u6392\u653e\u548c\u6cc4\u9732\u3002
\n– **\u56de\u6536\u518d\u5229\u7528**\uff1a\u5bf9\u542b\u6709TBT\u7684\u5e9f\u5f03\u7269\u8fdb\u884c\u56de\u6536\u5904\u7406\uff0c\u901a\u8fc7\u51c0\u5316\u540e\u91cd\u65b0\u6295\u5165\u751f\u4ea7\u6d41\u7a0b\u3002<\/p>\n

#### \u4e09\u3001\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u5bf9\u73af\u5883\u7684\u5f71\u54cd<\/p>\n

TBT\u56e0\u5176\u751f\u7269\u7d2f\u79ef\u6027\u548c\u751f\u6001\u6bd2\u6027\uff0c\u5bf9\u73af\u5883\u9020\u6210\u4e86\u663e\u8457\u5f71\u54cd\uff0c\u4e3b\u8981\u5305\u62ec\uff1a<\/p>\n

1. **\u751f\u7269\u7d2f\u79ef\u6027**\uff1aTBT\u5177\u6709\u8f83\u5f3a\u7684\u8102\u6eb6\u6027\uff0c\u5bb9\u6613\u901a\u8fc7\u98df\u7269\u94fe\u9010\u7ea7\u7d2f\u79ef\uff0c\u5bf9\u9876\u7ea7\u6355\u98df\u8005\u9020\u6210\u66f4\u5927\u5a01\u80c1\u3002
\n2. **\u751f\u6001\u6bd2\u6027**\uff1aTBT\u5bf9\u6c34\u751f\u751f\u7269\u5177\u6709\u5f3a\u70c8\u6bd2\u6027\uff0c\u5c24\u5176\u5bf9\u8d1d\u7c7b\u7b49\u6d77\u6d0b\u751f\u7269\u7684\u751f\u6b96\u7cfb\u7edf\u9020\u6210\u4e25\u91cd\u5e72\u6270\uff0c\u5f71\u54cd\u79cd\u7fa4\u7684\u7e41\u6b96\u80fd\u529b\u548c\u6027\u522b\u5206\u5316\u3002
\n3. **\u514d\u75ab\u7cfb\u7edf\u6291\u5236**\uff1aTBT\u80fd\u591f\u6291\u5236\u6c34\u751f\u751f\u7269\u7684\u514d\u75ab\u7cfb\u7edf\uff0c\u589e\u52a0\u5176\u5bf9\u75be\u75c5\u7684\u6613\u611f\u6027\u3002
\n4. **\u795e\u7ecf\u7cfb\u7edf\u635f\u5bb3**\uff1a\u9ad8\u6d53\u5ea6\u7684TBT\u66b4\u9732\u8fd8\u53ef\u80fd\u5bfc\u81f4\u6c34\u751f\u751f\u7269\u795e\u7ecf\u7cfb\u7edf\u7684\u635f\u4f24\uff0c\u5f71\u54cd\u5176\u884c\u4e3a\u548c\u751f\u5b58\u80fd\u529b\u3002<\/p>\n

#### \u56db\u3001\u73af\u5883\u5f71\u54cd\u8bc4\u4f30\u4e0e\u63a7\u5236\u7b56\u7565<\/p>\n

\u4e3a\u4e86\u8bc4\u4f30TBT\u5bf9\u73af\u5883\u7684\u5f71\u54cd\u5e76\u5236\u5b9a\u6709\u6548\u7684\u63a7\u5236\u7b56\u7565\uff0c\u9700\u8981\u91c7\u53d6\u4e00\u7cfb\u5217\u63aa\u65bd\uff1a<\/p>\n

1. **\u73af\u5883\u76d1\u6d4b**\uff1a\u5b9a\u671f\u5bf9\u6c34\u4f53\u3001\u5e95\u6ce5\u548c\u751f\u7269\u6837\u672c\u8fdb\u884c\u76d1\u6d4b\uff0c\u4ee5\u786e\u5b9aTBT\u7684\u5b58\u5728\u6c34\u5e73\u548c\u5206\u5e03\u60c5\u51b5\u3002
\n2. **\u98ce\u9669\u8bc4\u4f30**\uff1a\u7ed3\u5408TBT\u7684\u66b4\u9732\u9014\u5f84\u3001\u6bd2\u6027\u6548\u5e94\u548c\u751f\u6001\u7cfb\u7edf\u654f\u611f\u6027\u7b49\u56e0\u7d20\uff0c\u5efa\u7acb\u5168\u9762\u7684\u98ce\u9669\u8bc4\u4f30\u6846\u67b6\u3002
\n3. **\u6cd5\u5f8b\u76d1\u7ba1**\uff1a\u901a\u8fc7\u7acb\u6cd5\u9650\u5236\u6216\u7981\u6b62TBT\u5728\u67d0\u4e9b\u9ad8\u98ce\u9669\u9886\u57df\u7684\u4f7f\u7528\uff0c\u5982\u9632\u6c61\u6f06\u548c\u5176\u4ed6\u53ef\u80fd\u5bf9\u6c34\u4f53\u9020\u6210\u6c61\u67d3\u7684\u4ea7\u54c1\u3002
\n4. **\u66ff\u4ee3\u54c1\u5f00\u53d1**\uff1a\u79ef\u6781\u7814\u53d1\u66f4\u5b89\u5168\u3001\u73af\u4fdd\u7684\u66ff\u4ee3\u54c1\uff0c\u51cf\u5c11\u5bf9TBT\u7684\u9700\u6c42\u3002
\n5. **\u73af\u5883\u4fee\u590d**\uff1a\u5bf9\u4e8e\u5df2\u53d7\u6c61\u67d3\u7684\u533a\u57df\uff0c\u91c7\u7528\u7269\u7406\u3001\u5316\u5b66\u6216\u751f\u7269\u65b9\u6cd5\u8fdb\u884c\u73af\u5883\u4fee\u590d\u3002
\n6. **\u516c\u4f17\u6559\u80b2**\uff1a\u63d0\u9ad8\u516c\u4f17\u5bf9TBT\u7b49\u6709\u5bb3\u7269\u8d28\u7684\u8ba4\u8bc6\uff0c\u589e\u5f3a\u73af\u5883\u4fdd\u62a4\u610f\u8bc6\u3002<\/p>\n

#### \u4e94\u3001\u6848\u4f8b\u7814\u7a76<\/p>\n

\u4e00\u4e9b\u56fd\u5bb6\u548c\u5730\u533a\u5df2\u7ecf\u91c7\u53d6\u884c\u52a8\u6765\u5e94\u5bf9TBT\u9020\u6210\u7684\u73af\u5883\u6c61\u67d3\u3002\u4f8b\u5982\uff1a<\/p>\n

– **\u56fd\u9645\u5408\u4f5c**\uff1a\u56fd\u9645\u6d77\u4e8b\u7ec4\u7ec7\uff08IMO\uff09\u89c4\u5b9a\u4e86\u8239\u8236\u9632\u6c61\u6f06\u4e2dTBT\u7684\u4f7f\u7528\u9650\u5236\u3002
\n– **\u56fd\u5185\u7acb\u6cd5**\uff1a\u8bb8\u591a\u56fd\u5bb6\u548c\u5730\u533a\u901a\u8fc7\u7acb\u6cd5\u9650\u5236\u6216\u7981\u6b62TBT\u5728\u7279\u5b9a\u4ea7\u54c1\u4e2d\u7684\u4f7f\u7528\u3002
\n– **\u73af\u5883\u6cbb\u7406\u9879\u76ee**\uff1a\u5b9e\u65bd\u9488\u5bf9\u6027\u7684\u73af\u5883\u6cbb\u7406\u9879\u76ee\uff0c\u5982\u6cb3\u6d41\u3001\u6e56\u6cca\u548c\u6d77\u6d0b\u7684\u6e05\u6d01\u8ba1\u5212\u3002<\/p>\n

#### \u516d\u3001\u7ed3\u8bba<\/p>\n

\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u4f5c\u4e3a\u4e00\u79cd\u591a\u529f\u80fd\u7684\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\uff0c\u5728\u591a\u4e2a\u884c\u4e1a\u53d1\u6325\u7740\u91cd\u8981\u4f5c\u7528\u3002\u7136\u800c\uff0c\u5176\u5bf9\u73af\u5883\u7684\u8d1f\u9762\u5f71\u54cd\u4e0d\u5bb9\u5ffd\u89c6\u3002\u901a\u8fc7\u79d1\u5b66\u5408\u7406\u7684\u5904\u7406\u65b9\u6cd5\u548c\u4e25\u683c\u7684\u73af\u5883\u7ba1\u7406\u63aa\u65bd\uff0c\u53ef\u4ee5\u6709\u6548\u51cf\u5c11TBT\u5bf9\u73af\u5883\u7684\u6c61\u67d3\uff0c\u4fdd\u62a4\u751f\u6001\u5e73\u8861\u3002\u672a\u6765\u7684\u7814\u7a76\u65b9\u5411\u5c06\u66f4\u52a0\u6ce8\u91cd\u5f00\u53d1\u7eff\u8272\u66ff\u4ee3\u54c1\u548c\u63d0\u9ad8\u73b0\u6709\u5904\u7406\u6280\u672f\u7684\u6548\u7387\uff0c\u4ee5\u5b9e\u73b0\u7ecf\u6d4e\u4e0e\u73af\u5883\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u3002<\/p>\n

#### \u4e03\u3001\u5c55\u671b<\/p>\n

\u968f\u7740\u79d1\u6280\u7684\u8fdb\u6b65\u548c\u793e\u4f1a\u5bf9\u73af\u5883\u4fdd\u62a4\u610f\u8bc6\u7684\u63d0\u9ad8\uff0c\u9884\u8ba1\u5bf9TBT\u7b49\u6709\u5bb3\u7269\u8d28\u7684\u7ba1\u7406\u5c06\u66f4\u52a0\u4e25\u683c\u3002\u540c\u65f6\uff0c\u65b0\u578b\u6750\u6599\u548c\u5de5\u827a\u7684\u7814\u53d1\u4e5f\u5c06\u4e3a\u51cf\u5c11TBT\u7684\u4f7f\u7528\u63d0\u4f9b\u66f4\u591a\u7684\u53ef\u80fd\u6027\u3002\u672a\u6765\u7684\u7814\u7a76\u5de5\u4f5c\u5c06\u7ee7\u7eed\u81f4\u529b\u4e8e\u5bfb\u627e\u66f4\u73af\u4fdd\u7684\u66ff\u4ee3\u65b9\u6848\uff0c\u5e76\u6539\u5584\u73b0\u6709\u7684\u5904\u7406\u6280\u672f\uff0c\u4ee5\u51cf\u8f7bTBT\u5bf9\u73af\u5883\u7684\u957f\u671f\u5f71\u54cd\u3002<\/p>\n

—<\/p>\n

\u6269\u5c55\u9605\u8bfb\uff1a<\/p>\n

cyclohexylamine<\/u><\/a><\/p>\n

Tetrachloroethylene Perchloroethylene CAS:127-18-4<\/u><\/a><\/p>\n

NT CAT DMDEE<\/u><\/a><\/p>\n

NT CAT PC-5<\/u><\/a><\/p>\n

N-Methylmorpholine<\/u><\/a><\/p>\n

4-Formylmorpholine<\/u><\/a><\/p>\n

Toyocat TE tertiary amine catalyst Tosoh<\/u><\/a><\/p>\n

Toyocat RX5 catalyst trimethylhydroxyethyl ethylenediamine Tosoh<\/u><\/a><\/p>\n

NT CAT DMP-30<\/u><\/a><\/p>\n

NT CAT DMEA<\/u><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

### \u4e09\u4e01\u57fa\u6c27\u5316\u9521\u5904\u7406\u65b9\u6cd5\u53ca\u5176\u5bf9\u73af\u5883\u7684\u5f71\u54cd\u5206\u6790 #### \u5f15\u8a00 \u4e09\u4e01\u57fa\u6c27\u5316\u9521\uff08tributyltin oxide, TBT\uff09\u4f5c\u4e3a\u4e00\u79cd\u5e38\u89c1\u7684\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\uff0c\u5728\u5de5\u4e1a\u3001\u519c\u4e1a\u548c\u65e5\u5e38\u751f\u6d3b\u4e2d\u90fd\u6709\u5e7f\u6cdb\u5e94\u7528\u3002\u7136\u800c\uff0c\u5176\u5bf9\u73af\u5883\u5c24\u5176\u662f\u6c34\u751f\u751f\u6001\u7cfb\u7edf\u7684\u8d1f\u9762\u5f71\u54cd\u5f15\u8d77\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u672c\u6587\u65e8\u5728\u63a2\u8ba8TBT\u7684\u5904\u7406\u65b9\u6cd5\u53ca\u5176\u5bf9\u73af\u5883\u7684\u5f71\u54cd\u3002 #### \u4e00\u3001\u4e09\u4e01\u57fa …<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/posts\/7246"}],"collection":[{"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/comments?post=7246"}],"version-history":[{"count":2,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/posts\/7246\/revisions"}],"predecessor-version":[{"id":7248,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/posts\/7246\/revisions\/7248"}],"wp:attachment":[{"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/media?parent=7246"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/categories?post=7246"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.shigann.com\/wp-json\/wp\/v2\/tags?post=7246"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}